Synthesis and characterization of trans-Mo(CO)4(p-C5NH4SO3Na)2

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Date
2008-03-12
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Palabras Clave
Molybdenum, Pyridine-p-sulphonate, Carbonyl complexes
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Résumé
Reaction between Mo(CO)6 and p-C5NH4SO3Na (1:2 (Mo: p-C5NH4SO3Na) stoichiometric ratio) gave the trans-Mo(CO)4(p-C5NH4SO3Na)2 complex, (1), in 80% yield. Complex (1) has been characterized by FTIR, 1H and 13C NMR spectroscopy. Complex (1) has most likely an idealized D4h geometry with trans N-bound p-C5NH4SO3Na ligands.
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http://www.saber.ula.ve/handle/123456789/33631
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Correo Electrónicosuarez@ula.ve
fontal@ula.ve, bfontal@hotmail.com
reyes@ula.ve
bellandi@ula.ve
ricardo@ula.ve
cancines@ula.ve
fonsy@ula.ve
irc@cantv.net
EditorAkadémiai Kiadó, Budapest and Springer, Dordrecht
DescripciónArtículo Publicado en React.Kinet.Catal.Lett. Vol. 94, No. 1, 21−26 (2008)