SABER-ULA, Universidad de Los Andes - Mérida - Venezuela >
Facultades >
Facultad de Ingeniería >
Unidades de Investigación de la Facultad de Ingeniería >
Laboratorios de Investigación >
Laboratorio de Formulación, Interfaces, Reología y Procesos (FIRP) >
Articulos, Pre-prints (Laboratorio de Formulación, Interfaces, Reología y Procesos (FIRP)) >


Título: Optimum phase-behavior formulation of surfactant/oil/water systems for the determination of chromium in heavy crude oil and in bitumen-in-water emulsion
Autores: Burguera, José Luis
Pascu de Burguera, Marcela
Burguera Pascu, Constantin R.
Ávila G., Rita M.
Salager, Jean Louis
Bracho P., Carlos L.
Antón, Raquel E.
Burguera Pascu, Margarita
Brunetto, Rosario
Gallignani, Maximo A.
Petit de P., Yaneira
Correo Electrónico: burguera@ula.ve
pascu@ula.ve
ritaavila@ucla.edu.ve
salager@ula.ve
bracho@ula.ve
rantons@cantv.net
ypetit@ula.ve
Editor: SABER ULA
Resumen: Optimum phase-behavior formulation of surfactant/oil/water systems for the determination of chromium in heavy crude oil and in bitumen-in-water emulsion. (Burguera, José L.; Ávila G., Rita M.; Pascu de Burguera, Marcela; Antón, Raquel E.; Salager, Jean Louis; Bracho P., Carlos L.; Burguera Pascu, Margarita; Burguera Pascu, Constantin R.; Brunetto, Rosario; Gallignani, Maximo A.; Petit de P., Yaneira) Abstract An "oil in water" formulation was optimized to determine chromium in heavy crude oil (HCO) and bitumen-in-water emulsion (Orimulsion-400®) samples by transversally heated electrothermal atomic absorption spectrometry (TH-ET AAS) using Zeeman effect background correction. The optimum proportion of the oil-water mixture ratio was 7:3 v/v (70 ml of oil as the internal phase) with a non-ionic surfactant concentration (lntan-l00) in the emulsion of 0.2% w/w. Chromium was determined in different crude oil samples after dilution of the emulsions 1:9 v/v with a 0.2°/, w/w solution of surfactant in order to further reduce the viscosity from 100 to 1.6 cP and at the same time to bring the concentration of chromium within the working range of the ET AAS technique. The calibration graph was linear from 1.7 to 100 gg Cr 1- t. The sensitivity was of 0.0069 s 1 µg- ', the characteristic mass (mo) was of 5.7 pg per 0.0044 s and the detection limit (36) was of 0.52 pg 1-'. The relative standard deviation of the method, evaluated by replicate analyses of three crude oil samples varied in all cases between 1.5 and 2.6%. Recovery studies were performed on four Venezuelan crude oils, and the average chromium recovery values varied between 95.9-104.8, 90.6-107.6, 95.6-104.0 and 98.8-103.9% for the Cerro Negro, Crudo Hamaca and Boscan crude oils and for the Orimulsion®-400, respectively. The results obtained in this work for the Cerro Negro, Crudo Hamaca and Boscan crude oils and for the Orimulsion('~-400 following the proposed procedure were of 0.448±0.008, 0.338±0.004 0.524±0.021 and 0.174±0.008 mg Cr 1-t, respectively, which were in good agreement with the values obtained by a tedious recommended standard procedure (respectively: 0.470±0.05, 0.335±0.080, 0.570±0.021 and 0.173±0.009 mg Cr 1-t). CC) 2003 Elsevier B.V. All rights reserved. Artículo publicado en: Talanta 61 (2003) 353-361
Fecha: 1-Feb-2006
Palabras Clave: Heavy crude oils
Three-phase behavior
ET AAS
Chromium
URI: http://www.saber.ula.ve/handle/123456789/15787
Aparece en colecciones:Articulos, Pre-prints (Laboratorio de Formulación, Interfaces, Reología y Procesos (FIRP))
Articulos, Pre-prints (Facultad de Odontología)
Artículos, Pre-prints (Facultad de Ingeniería)
Articulos, Pre-prints (Facultad de Ciencias)

Archivos en estos artículos:

Archivo Descripción TamañoFormato
optimum-phase.pdf778.62 kBAdobe PDFVer/Abrir
resumen.htm2.54 kBHTMLVer/Abrir

Todos los artículos en Dspace están protegidos con Derecho de Autor, todos los derechos reservados, a menos que se indique lo contrario.

 

Licencia Creative Commons
Todos los documentos publicados en este repositorio se distribuyen bajo una
Licencia Creative Commons Atribución-NoComercial-CompartirIgual 3.0 Venezuela.

Repositorio Institucional de la Universidad de Los Andes, Mérida, Venezuela - Comentarios
Software DSpace Copyright © 2002-2007 MIT and Hewlett-Packard -
DSpace Add-on Statistics of RepositóriUM © University of Minho.