Listar Unidades de Investigación de la Facultad de Ciencias por autor "Cancines, Pedro I."

Mostrando ítems 1-6 de 6

    • Hydroformylation reactions of the trans-Mo(CO)4(p-C5NH4SO3NA)2 complex in biphasic medium 

      Suárez B., Trino; Fontal, Bernardo; Zambrano, Ghery; Reyes, Marisela del C.; Bellandi, Fernando; Contreras, Ricardo Rafael; Díaz, Juan C.; Cancines, Pedro I.; Fonseca V., Yuraima J.; Romero C., Isolda (Akadémiai Kiadó, Budapest and Springer, Dordrecht, 2008-10-12)
      Trans-bis(sodium pyridine-p-sulphonate)tetracarbonylmolybdenum(0) complex, (trans-Mo(CO)4(p-PySO3Na)2, (1)) was used as a catalytic precursor for the 1- hexene hydroformylation reaction, in biphasic toluene/water medium ...

    • Información Investigador: Cancines Moreno, Pedro Ignacio 

      Cancines, Pedro I. (2008-09-19)
      Resumen Curricular Licencia en Educación Mención Química, 13/09/1991, Estudios de Postgrado en la Mención estudio de Materiales del PIQA. Publicaciones internacionales en el campo de la catálisis homogénea y ...

    • Synthesis and characterization of trans-Mo(CO)4(p-C5NH4SO3Na)2 

      Suárez B., Trino; Fontal, Bernardo; Zambrano, Ghery; Reyes, Marisela del C.; Bellandi, Fernando; Contreras, Ricardo Rafael; Díaz, Juan C.; Cancines, Pedro I.; Fonseca V., Yuraima J.; Romero C., Isolda (Akadémiai Kiadó, Budapest and Springer, Dordrecht, 2008-03-12)
      Reaction between Mo(CO)6 and p-C5NH4SO3Na (1:2 (Mo: p-C5NH4SO3Na) stoichiometric ratio) gave the trans-Mo(CO)4(p-C5NH4SO3Na)2 complex, (1), in 80% yield. Complex (1) has been characterized by FTIR, 1H and 13C NMR spectroscopy. ...

    • Synthesis, characterization and hydroformylation catalytic activity of a water-soluble RhCl(CO)(PySO3Na)2 complex using 1-hexene and real naphtha 

      Fonseca V., Yuraima J.; Fontal, Bernardo; Reyes, Marisela del C.; Suárez B., Trino; Bellandi, Fernando; Díaz, Juan C.; Cancines, Pedro I. (2012-03-16)
      In this work, we describe the synthesis and characterization of a new water soluble [RhCl(CO)(PySO3Na)2], complex (1); where [PySO3Na] is the sodium salt of p-sulfonated pyridine ligand. Complex (1) was obtained in methanol, ...

    • Synthesis, characterization and olefin hydroformylation reactions of mer-[Mo(CO)3(p-C5H4N-CN)3] 

      Suárez B., Trino; Fontal, Bernardo; Parra, María F.; Reyes, Marisela del C.; Bellandi, Fernando; Díaz, Juan C.; Cancines, Pedro I.; Fonseca V., Yuraima J. (Springer Science+Business Media B.V. 2010, 2010-01-12)
      Mer-[Mo(CO)3(p-C5H4N-CN)3] was prepared by UV-irradiation of a THF solution of Mo(CO)6 and paracyanopyridine under heating. The complex was characterized by FT-IR, MS, 1H and 13C NMR and showed catalytic activity for olefin ...

    • Synthesis, characterization, and biphasic ionic liquid media 1-hexene hydrogenation reaction of RuCl2(DMSO)2(NC5H4CO2Na-3)2 

      Suárez B., Trino; Fontal, Bernardo; Vielma, Joel E.; Reyes, Marisela del C.; Bellandi, Fernando; Cancines, Pedro I.; Díaz, Juan C.; Fonseca V., Yuraima J. (Publicado en Science+Business Media B.V., 2011-06)
      RuCl2(DMSO)2(NC5H4CO2Na-3)2 is very soluble in the ionic liquid (IL) 1-n-butyl-3-methylimidazolium tetrafluoroborate, [(BMIM)BF4]. The complex was prepared by reacting RuCl2(DMSO)4 with NC5H4CO2Na-3, sodium nicotinate, in ...