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Aqueous biphasic olefin hydroformylation catalyzed by water-soluble rhodium complexes
(2011-08-17)
Catalysis with water-soluble rhodium complexes, RhCl(CO)(TPPMS)2, [TPPMS = P(C6H5)2(C6H4SO3)] (1),
RhCl(CO)(TPPDS)2, [TPPDS = P(C6H5)(C6H4SO3)2] (2) and RhCl(CO)(TPPTS)2, [TPPTS = P(C6H4SO3)3] (3)
in hydroformylation of ...
Hydrogenation of aromatics with [Ru(g5-C5H5)Cl(TPPDS)2] in biphasic medium
(2011-08-16)
[Ru(g5-C5H5)Cl(TPPDS)2], [TPPDS=P(C6H5)(C6H4SO3
))2] in biphasic (n-heptane/water) medium hydrogenates
toluene, benzene and m-xylene (105 C, 1400 psig H2, substrate/catalyst=600:1, 4 h) and in toluene hydrogenation
gives ...