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Hydrogenation of aromatics with [Ru(g5-C5H5)Cl(TPPDS)2] in biphasic medium
(2011-08-16)
[Ru(g5-C5H5)Cl(TPPDS)2], [TPPDS=P(C6H5)(C6H4SO3
))2] in biphasic (n-heptane/water) medium hydrogenates
toluene, benzene and m-xylene (105 C, 1400 psig H2, substrate/catalyst=600:1, 4 h) and in toluene hydrogenation
gives ...